(E)-4-Chloro-N-[4-(methylsulfonyl)benzylidene]aniline
نویسندگان
چکیده
In the crystal structure of the title compound, C(14)H(12)ClNO(2)S, the mol-ecules display a trans conformation with respect to the C=N double bond. The dihedral angle between the methyl-sulfonyl benzene and chloro-benzene rings is 59.59 (8)°. The crystal packing is stabilized by weak C-H⋯O inter-actions and by π-π stacking inter-actions between inversion-related methyl-sulfonyl benzene rings [centroid-centroid distance = 3.8579 (11) Å].
منابع مشابه
(E)-2-Methyl-N-[4-(methylsulfonyl)benzylidene]aniline
Mol-ecules of the title compound, C(15)H(15)NO(2)S, display an E configuration with respect to the C=N double bond. The crystal structure is stabilized by weak C-H⋯O hydrogen bonds. The dihedral angle between the two aromatic ring planes is 50.41 (12)°.
متن کامل(E)-N-[4-(Methylsulfonyl)benzylidene]aniline
The mol-ecule of the title compound, C(14)H(13)NO(2)S, displays a trans configuration with respect to the C=N double bond. The dihedral angle between the two aromatic ring planes is 62.07 (18)°.
متن کامل4-Chloro-N-[4-(diethylamino)benzylidene]aniline
The asymmetric unit of the title compound, C(17)H(19)ClN(2), contains two independent mol-ecules which differ by a 180° flip in the orientation of the 4-chloro-aniline unit with respect to the diethyl-amino-benzyl-idene unit [N=C-C-C = 10.0 (3) and -170.6 (2)°]. The dihedral angles between the two aromatic rings are 64.0 (1) and 66.5 (1)° in the two independent mol-ecules.
متن کامل2-Chloro-N-[4-(dimethylamino)benzylidene]aniline
In the title mol-ecule, C(15)H(15)ClN(2), the dihedral angle between the aromatic is 64.1 (2)°.
متن کاملN-[(E)-4-(Methylsulfonyl)benzylidene]-3-nitroaniline
In the title compound, C(14)H(12)N(2)O(4)S, the dihedral angle between the two aromatic rings is 35.65 (12)°. The crystal packing is stabilized by weak C-H⋯O hydrogen bonds and aromatic π-π ring stacking inter-actions [minimum ring centroid separation = 3.697 (3) Å].
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012